News TV Videos ‘The Blacklist’ opening scene – Watch Charles Baker from ‘Breaking Bad’ Monday on NBC Written by Lena Lamoray on September 18, 2013 The Blacklist: Opening Scene – Watch the entire first scene of what USA Today calls “Fall’s best new drama,” premiering Monday Sept 23 at 10/9c on NBC. Related posts:Exclusive Interview: Demetrius Grosse discusses 'Game of Silence,' 'Westworld,' 'Justified' and more'Grimm' series finale previewKevin Bacon's 'Footloose' entrance