News TV Videos ‘The Blacklist’ opening scene – Watch Charles Baker from ‘Breaking Bad’ Monday on NBC Written by Lena Lamoray on September 18, 2013 The Blacklist: Opening Scene – Watch the entire first scene of what USA Today calls “Fall’s best new drama,” premiering Monday Sept 23 at 10/9c on NBC. Related posts:Showtime announces premiere date for season two of 'Your Honor''Grimm' season finale preview and interviews with David Giuntoli, Silas Weir Mitchell, and Bree Turn...'Chicago Fire' preview